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Search for "multivalent anchoring" in Full Text gives 1 result(s) in Beilstein Journal of Nanotechnology.

Rigid multipodal platforms for metal surfaces

Michal Valášek,
Marcin Lindner and
Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

over the arrangement of the protruding rod-type molecular structures (e.g., molecular wires, switches, rotors, sensors) with respect to the surface of the substrate. Keywords: multivalent anchoring; protruding structure; spatial arrangement; tripodal platform; Introduction Molecular electronics, as

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Figure 1: Schematic drawing of a molecule attached to the surface via a tripodal structure.

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Figure 2: Aliphatic tripodal structures 1–5.

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Figure 3: Trialkylarylsilane platforms 6–8.

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Figure 4: Structure of extended adamantane-based scaffolds 9–12.

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Figure 5: Structure of adamantane tripodal molecules 13–16.

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Figure 6: (a) UHV-NC-AFM image (350 × 350 nm², Δf = −28 Hz) of 4-carboxyazobenzene 13 adsorbed on Au(111) usi...

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Figure 7: Adamantane-based tripods 17–20.

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Figure 8: (a) ORTEP drawing of 17 as determined by single-crystal X-ray diffraction analysis at 100 K. Ellips...

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Figure 9: Schematic adsorption models of trimers (a), hexagon (b) and SAMs (c) of 17 on Au(111). B (B’) is th...

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Figure 10: Adamantane and cyclohexane-based tridental platforms.

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Figure 11: Structure of aliphatic multipodal adsorbates.

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Figure 12: Functionalized tetraphenylmethane tripods 29–32.

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Figure 13: Structure of pyridine terminated platforms 33–35.

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Figure 14: Structures of the junctions used for the ab initio transport calculations, (a) 34 (111) model and (...

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Figure 15: Redox-active tripodal structures 36 and 37.

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Figure 16: Self-decoupled porphyrin with a tetraphenylmethane scaffold 38.

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Figure 17: Schematic configuration of 38 on Au(111) and localized electrical excitation from a nanotip. Reprin...

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Figure 18: Structure of tripodal [2]rotaxanes 39.

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Figure 19: Tetraphenylsilane-based platforms 40.

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Figure 20: Structure of surface-bound molecular motors 41 for gold surfaces.

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Figure 21: Fullerene-terminated tetraphenylmethane platforms 42 and 43.

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Figure 22: Structure of the tripodal luminescent ruthenium complex 44.

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Figure 23: Bis(terpyridine)–Fe(II) oligomer wires terminated with a tripodal scaffold 45.

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Figure 24: Structure of altitudinal light-driven molecular motors 46 and 47 for gold surfaces.

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Figure 25: Structure of the rigid 9,9’-spirobifluorene platform 48.

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Figure 26: (a) Highly ordered island of molecular tripods 48 (yellow) and remaining CH₂Cl₂ (dark purple) on th...

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Figure 27: Organometallic tripodal scaffolds 49–51.

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Figure 28: Dipolar and nonpolar altitudinal molecular rotors 52 and 53.

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Figure 29: Optimized representative eclipsed (A) and staggered (B) conformations of the MMP diastereomer of 52...

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Figure 30: Structure of triazatriangulenium 54 and trioxatriangulenium 55 scaffolds.

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Figure 31: (a) STM image of a porphyrin–TATA adlayer of a zinc-porphyrin derivative of the octyl-TATA platform ...

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Review

Published 08 Mar 2016

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